（16）烴類(lèi)—蒸汽轉(zhuǎn)化制氫裝置年度匯編

1、355一、裝置概況表1序號(hào)廠名(裝置簡(jiǎn)稱(chēng))加工能力2008年開(kāi)工天數(shù)建設(shè)日期設(shè)計(jì)單位占地面積投資目前主要設(shè)備概況初建設(shè)計(jì)2008年止改造后2008年度產(chǎn)氫量負(fù)荷率投產(chǎn)改造初建設(shè)計(jì)改造設(shè)計(jì)初建改造投資塔加熱爐冷換設(shè)備反應(yīng)器機(jī)泵容器萬(wàn)噸/年萬(wàn)噸/年噸/年%天年 月年 月m2萬(wàn)元萬(wàn)元座座臺(tái)臺(tái)臺(tái)臺(tái)合計(jì)68.073.036976857.44263.6上市67.672.636831557.52260.6非上市0.40.4145340.36353.01燕山 ()1.51.51044868.34349.02001.05洛陽(yáng)院567111976921041427 ()3.83.83152484.05356.02

2、007.06202901116443582天津 ()1.42.3未開(kāi)工1999.042008.09北京院13500111441648 ()1.41.4864161.72252.01998.11北京院135001114516493石家莊1.01.0630463.04337.02002.042005.06北京院399010390102548264滄州 0.70.7208228.92285.02001.12北京院540014000425512375濟(jì)南 1.51.5未開(kāi)工2002.12北京院540014000221045336齊魯 ()1.52.92152774.75349.01982.041999

3、.10齊魯石化齊魯石化830074001133384547 ()3.13.52879681.44351.01991.042005.03本單位華西所1080087003230627697勝石化0.50.7217833.15324.01996.072003.06蘭州院洛陽(yáng)院512025001508921055218金陵 ()1.82.31005844.70249.01986.092003.12洛陽(yáng)院大連天邦.金陵院6300247010003225622259揚(yáng)子 5.35.321820135.08328.31990.01西德魯奇196201285613308155910 武漢 ()0.40.649

4、0976.61333.01997.011999.12蘭化院北京院480020001129629611 荊門(mén) 2.83.41317838.87361.02002.092002.05北京院洛陽(yáng)院1200120084375294212 長(zhǎng)嶺 1.41.4490334.32316.01989.101994.11北京院本單位120004570650733574819356續(xù)表1序號(hào)廠名(裝置簡(jiǎn)稱(chēng))加工能力2008年開(kāi)工天數(shù)建設(shè)日期設(shè)計(jì)單位占地面積投資目前主要設(shè)備概況初建設(shè)計(jì)2008年止改造后2008年度產(chǎn)氫量負(fù)荷率投產(chǎn)改造初建設(shè)計(jì)改造設(shè)計(jì)初建改造投資塔加熱爐冷換設(shè)備反應(yīng)器機(jī)泵容器萬(wàn)噸/年萬(wàn)噸/年噸/年%

5、天年 月年 月m2萬(wàn)元萬(wàn)元座座臺(tái)臺(tái)臺(tái)臺(tái)13 高橋 ()1.451.45502734.67183.92002.05北京院11145221441633 ()2.92.9992634.23176.12004.10北京院1849711125109 ()1.91.9844944.47225.42008.04北京院12328200551215462914 上海石化3.13.12141668.64335.01984.012003.09德國(guó)魯奇四川天一132361132 ()2.32.32061090.17311.02002.0811182162515 鎮(zhèn)海 ()1.82.219208.8942.01993.

6、052001.08洛陽(yáng)院洛陽(yáng)院980052272000322162121 ()1.82.21233457.10341.01993.052001.08洛陽(yáng)院洛陽(yáng)院98005227200032206212216 廣州 ()2.62.61949774.27326.22006.08東華工程公司11114121561010 ()4.94.94684496.09361.32006.11東華科技500007326815817 茂名 ()1.81.8未開(kāi)工1982.10洛陽(yáng)院67384000233262023 ()1.81.8未開(kāi)工1982.11洛陽(yáng)院67884500433472226 ()4.34.3294

7、5968.96366.01999.11洛陽(yáng)院1050028140121315222618 杭州 0.40.4145340.36353.02003.06洛陽(yáng)院27454000927571319 塔河 1.81.8506027.65366.02004.1111946820 西安 0.30.3未開(kāi)工2004.08洛陽(yáng)院924621 海南 4.54.51334229.65360.02006.08洛陽(yáng)院1482025935151214204822 青島煉化2.42.4806333.86235.02008.04寧波工程公司1127411841114357二、原料、成品、半成品理化性質(zhì)1.原料理化性質(zhì)（液體

8、）(1)表2-1序號(hào)廠名(裝置簡(jiǎn)稱(chēng))原料名稱(chēng)密度(20)餾程族組成總含硫量雜質(zhì)含量HK10%30%50%70%90%KK烷烴環(huán)烷烴芳烴烯烴AsCl-kg/m3%ppmppmppm1天津 ()石腦油705.033651081441684.100.751812齊魯 ()拔頭油648.226324043516311899.600.300.101001 ()石腦油642.32834404551677899.300.700.001023揚(yáng)子 輕石腦油639.3313640455259642.534荊門(mén) 輕石腦油695.0303545528010114552.7243.403.200.50205高橋 ()

9、輕石腦油710.03616363.8528.857.300.000.5 ()輕石腦油710.03616363.8528.857.300.000.56上海石化()輕石腦油640.0242840616691.806.861.350.001.0 ()LPG0.467廣州 ()0.00 ()石腦油650.13012050.8643.126.020.0015.408茂名 ()輕石腦油0.009杭州 輕石腦油700.05016097.002.001.152010 海南 輕石腦油634.03133415052670.040.70303581.原料理化性質(zhì)（氣體）(2)表2-2序號(hào)廠名(裝置簡(jiǎn)稱(chēng))原料名稱(chēng)分子

10、量氫碳比H/C組成總SH2CH4C2H6大于C2COCO2O2烯烴%(v)%(v)%(v)%(v)%(v)%(v)%(v)%(v)%(v)1燕山 ()天然氣164.000.0091.882.850.610.001.800.960.000.00 ()天然氣173.980.0495.500.600.120.000.010.000.000.012天津 ()干氣124.2047.6812.4315.270.000.000.000.003石家莊焦化干氣223.3113.8044.6425.4011.320.000.000.005.280.004滄州 焦化干氣+加氫干氣287.9349.1710.8125

11、.548.985齊魯 ()瓦斯氣+天然氣153.4029.0239.6710.0418.450.001.080.290.300.00 ()天然氣+煉廠凈化氣193.7933.8345.444.1012.000.601.400.706勝石化混合干氣203.3332.0015.0011.5023.000.720.770.909.500.027金陵 ()加氫干氣124.7271.5010.401.9016.200.000.008揚(yáng)子 天然氣94.731.970.561.009武漢 ()催化干氣27.3637.7712.264.321.231.0312.9316.880.0210 荊門(mén) 252.201

12、3.4043.5013.487.050.810.120.503.900.0211 長(zhǎng)嶺 焦化干氣173.6724.9051.8017.543.3712 高橋 ()混合干氣223.4238.1618.6014.5123.430.000.011.171.790.00 ()混合干氣223.4238.1618.6014.5123.430.000.011.171.790.00 ()干氣2028.8233.7617.8413.120.000.000.902.7413 上海石化()液化氣570.8599.150.601.00 ()甲烷氫164.219.4990.030.50359續(xù)表2-2序號(hào)廠名(裝置簡(jiǎn)稱(chēng)

13、)原料名稱(chēng)分子量氫碳比H/C組成總SH2CH4C2H6大于C2COCO2O2烯烴%(v)%(v)%(v)%(v)%(v)%(v)%(v)%(v)%(v)14 鎮(zhèn)海 ()干氣+天然氣144.2753.6623.8310.1012.410.170.000.001.96 ()干氣+天然氣213.5130.0819.749.4940.690.000.000.000.040.0015 廣州 ()加氫尾氣+焦化、重催干氣+中壓瓦斯183.7132.8933.3312.436.090.000.000.117.700.09 ()加裂尾氣1155.6735.724.863.750.000.000.000.000

14、.0016 茂名 ()加氫干氣124.5760.2020.917.7911.100.010.020.250.0117 杭州 催化干氣2142.0025.0012.000.0013.000.0018 塔河 天然氣183.8288.283.910.100.480.000.0019 海南 重整氫PSA尾氣70.0012.507.908.000.005.0020 青島煉化天然氣183.760.1094.202.880.270.001.210.460.880.003602.成品、半成品組成表2-3序號(hào)廠名(裝置簡(jiǎn)稱(chēng))成品、半成品名稱(chēng)組成氫氣甲烷一氧化碳二氧化碳%(v)%(v)ppmppm1燕山 ()99

15、.900.000.500.20 ()氫氣99.900.1020.001.002天津 ()氫氣99.990.752.613石家莊99.990.004.500.404齊魯 ()工業(yè)氫氣97.002.808.206.50 ()產(chǎn)品氫氣99.905.0011.0014.005勝石化工業(yè)氫99.900.0210.0020.006金陵 ()95.104.901.0039.007揚(yáng)子氫氣99.99 轉(zhuǎn)化氣79.014.197.908.90 高變氣80.424.100.8614.628武漢 ()中變氣74.763.530.9616.029荊門(mén) 工業(yè)氫97.803.200.000.0010 長(zhǎng)嶺 甲醇原料氣75

16、.402.1010.7011.8011 高橋 ()99.900.1010.0010.00 ()99.900.1010.0010.00 ()99.990.003.165.8512 上海石化()氫氣99.990.0156361續(xù)表2-3序號(hào)廠名(裝置簡(jiǎn)稱(chēng))成品、半成品名稱(chēng)組成氫氣甲烷一氧化碳二氧化碳%(v)%(v)ppmppm ()氫氣99.992.814.4513 鎮(zhèn)海 ()96.583.421.0012.95 ()96.653.353.0010.8014 廣州 ()99.920.011.125.21 ()95.624.383.121.0215 茂名 ()工業(yè)氫99.900.0085.1220.

17、5116 杭州 99.9917 海南 99.900.010.0015.6018 青島煉化99.900.006.304.78362三、主要操作條件1、操作條件（1）表3-1序號(hào)廠名(裝置簡(jiǎn)稱(chēng))原料預(yù)熱爐加氫反應(yīng)器脫硫反應(yīng)器轉(zhuǎn)化反應(yīng)器（爐）工業(yè)廢熱鍋爐入出口油溫度(入/出)爐管壓降煙氣溫度入出口油溫度(入/出)床層壓降干氣空速入出口油溫度(入/出)床層壓降干氣空速出口氣含H2S量入口溫度出口溫度入口壓力床層壓降總碳空速水碳比入口溫度出口溫度入口壓力KPaKPah-1KPah-1ppmMPaKPah-1H2O/CMPa1燕山 ()75/38045170375/36510.0355/32020.00.

18、25068032.62180599.73.65 ()333/3288.01049328/32311.0482.00.55008052.60300708.03.908003302.302天津 ()247/360128158359/3496.01500349/3357.0330.00.34727702.78190420.03.897803402.603石家莊84/3042263110.01335/32830.014707601.7290465.03.658003501.714滄州 65/267213240/3121.85307/2822.040.00.54597632.1760300.05.335

19、齊魯 ()60/355310350335/35020.0910345/34028.0460.00.54907601.80180780.05.007603451.80 ()220/320500400323/31546.0696315/301100.0343.004807802.90495.04.807703442.446勝石化240/3501.6300350/3002.8200.004907601.54160420.05.506803401.387金陵 ()20/28230282/357100357/32150.00.54477791.81192392.84.507793801.628揚(yáng)子355

20、.4/349.5/4827442.514.52 352.7/347.9/4837252.444.219武漢 ()220/350300/3300.54757401.601205.0074035010 荊門(mén) 60/34050435320/35020.070332/27920.025.00.34707801.605050.05.207803301.5511 長(zhǎng)嶺 40/23540195235/37022.0145350/30526.063.80.35107151.26100315.03.907153301.2612 高橋 ()300/330320/3100.55107702.261403.80 ()

21、310/350340/3300.55307902.463003.70 ()293/3496.0360349/3355.0346.40.54997702.351534.107703292.113 上海石化355/357348/34414397872.81583.107803602.50363續(xù)表3-1序號(hào)廠名(裝置簡(jiǎn)稱(chēng))原料預(yù)熱爐加氫反應(yīng)器脫硫反應(yīng)器轉(zhuǎn)化反應(yīng)器（爐）工業(yè)廢熱鍋爐入出口油溫度(入/出)爐管壓降煙氣溫度入出口油溫度(入/出)床層壓降干氣空速入出口油溫度(入/出)床層壓降干氣空速出口氣含H2S量入口溫度出口溫度入口壓力床層壓降總碳空速水碳比入口溫度出口溫度入口壓力KPaKPah-1KP

22、ah-1ppmMPaKPah-1H2O/CMPa ()311/33917.211565287872.62124599.23.6414 鎮(zhèn)海 ()36/36750390367/35520.0423355/32320.00119.4814827541.90140626.74.107543301.97 ()33/37060413370/36025.0431360/32920.00121.7814697371.90190622.24.017373221.9715 廣州 ()282/38899.0375/3520.55058003.062403.918003442.82 ()70/380182380/3

23、78365/34520.120.54908003.11604.127983902.7516 茂名 ()335/354354/3440.55107352.78100287.04.5017 杭州 25/36013260/3300.5345/36005007252.45600.06.006683162.1618 塔河 316/30110.0665295/26940.00317.000.185477382.43374614.03.507383742.0619 海南 360/35510.0600355/34010.00600.000.55007202.1560300.05.507403422.1020

24、青島煉化320/3603.0380320/3003.00150.0000.15007402.3080350.03.808003302.203642、操作條件（2）表3-2序號(hào)廠名(裝置簡(jiǎn)稱(chēng))生產(chǎn)蒸汽中變反應(yīng)器低變反應(yīng)器甲烷化反應(yīng)器壓力產(chǎn)量溫度入口溫度出口溫度入口壓力床層壓降干氣空速CO含量(入/出）入口溫度出口溫度入口壓力床層壓降干氣空速CO含量(入口)入口溫度出口溫度床層熱點(diǎn)溫度入口壓力床層壓降入CO+CO2出CO+CO2干氣空速M(fèi)Pat/hMPaKPah-1%MPaKPah-1%MPaKPa%ppmh-11燕山 ()3.8725.004103604082.3010.008.05/12.98

25、 ()3.5075.003903223702.2563.00151110.01/16.012天津 ()3.5035.004103513962.3056.002256.5/16.73石家莊3.6616.004453503921.716304滄州 3.009.182343383632.141.70755齊魯 ()2.5048.002333453951.6065.0010151902001.499251.502852912931.450.0316.321490 ()3.3053.002403463812.322002508.8/0.96勝石化1.807.002303403801.3710015001

26、4/207金陵 ()3.7726.304273804191.5950.0017565.2/1.71861961.395017471.703033103101.21500.1+0.11+398揚(yáng)子3523912.36 3583982.329武漢 ()1.903503901.6010 荊門(mén) 2.0020.002303303801.5520.003508.14/1.641801921.50203500.012703203451.30200.020.00372011 長(zhǎng)嶺 1.678.6020512 高橋 ()3.4029.003803603652.1212.0010/1.63904504502.33

27、43 ()3.4062.004083803802.1810/2.24004604602.62100 ()3.1045.002403293622.11502878.92/1.0913 上海石化3.5020.00320330390365續(xù)表3-2序號(hào)廠名(裝置簡(jiǎn)稱(chēng))生產(chǎn)蒸汽中變反應(yīng)器低變反應(yīng)器甲烷化反應(yīng)器壓力產(chǎn)量溫度入口溫度出口溫度入口壓力床層壓降干氣空速CO含量(入/出）入口溫度出口溫度入口壓力床層壓降干氣空速CO含量(入口)入口溫度出口溫度床層熱點(diǎn)溫度入口壓力床層壓降入CO+CO2出CO+CO2干氣空速M(fèi)Pat/hMPaKPah-1%MPaKPah-1%MPaKPa%ppmh-1 ()3.50

28、49.6040034338720.3312859.87/1.6814 鎮(zhèn)海 ()3.8227.082543273721.6010.0012969.30/1.341912001.501011981.342802942971.25200.2428.203066 ()3.8725.222523143621.6010.0017228.39/1.461891951.501315911.462802922941.25200.2110.80220315 廣州 ()6.9750.222903443822.8160.129.82/1.582022052.746.111.58 ()7.2850.652903904

29、292.75120.121952102.7110.22822983002.53100.302.3016 茂名 ()3.6275.004283433892.59100102310/1.42102192.565011301.4017 杭州 3353253352.1215018 塔河 3.617.304283734062.0460.0012808/0.9619 海南 3.5035.004103453802.1020.008009/1.120 青島煉化3.6013.004003353752.2035.003001.53663、操作條件（3）表3-3序號(hào)廠名(裝置簡(jiǎn)稱(chēng))脫CO2塔再生塔總堿度K2CO3K

30、HCO3總釩入口溫度出口溫度入口壓力壓降出口氣中CO2含量吸收能力富液入口溫度塔頂出口溫度塔底壓力貧液轉(zhuǎn)化率(相對(duì))半貧液轉(zhuǎn)化率(相對(duì))富液半貧液貧液富液半貧液貧液富液半貧液貧液富液半貧液 貧液MPaKPa%CO2Nm3/m3MPa%1燕山 ()0.002齊魯 ()95651.44180.0526.0098910.04 22.0041.012.9021.3013.197.070.693金陵 ()115621.26500.10109960.1125.2138.7121.1510.331.444荊門(mén) 106881.3200.017.0099940.15 95.0095.01251301.101.0

31、1.15鎮(zhèn)海 ()111631.3300.0896890.0317.1236.2722.7421.9623.499.3214.3219.4019.45 11.085.923.163.15 () 108661.22350.0594890.0811.5343.2912.2622.3625.449.3312.6822.5119.35 14.034.250.596廣州 ()71822.55 0.80.030.0615.1233.35195.18 220.16192.35 275.7894.68 48.326.157.08367 4、操作條件（4）表3-4序號(hào)廠名(裝置簡(jiǎn)稱(chēng))V+5三乙醇胺二乙醇三胺總鐵

32、再生度泡沫高度消泡時(shí)間富液半貧液貧液富液半貧液貧液富液半貧液貧液富液半貧液貧液富液半貧液貧液富液半貧液貧液富液半貧液貧液消泡時(shí)間%ppmppmppm%cmcmcmsss1齊魯 ()0.391.301.6041.051.501.801.601.902金陵 ()0.752.1436.707.803.003荊門(mén) 0.840.830.8417.0022.0024.001.351.104鎮(zhèn)海 ()0.402.0938.255.583.428.453.612.164.39 ()0.362.1130.307.505.503.003.502.201.005廣州 ()2.782.3520.3869.120.51

33、1.00368四、物料平衡表4序號(hào)廠名(裝置簡(jiǎn)稱(chēng))進(jìn)料量百分率出料量產(chǎn)品產(chǎn)率原料水蒸汽配氫氣合計(jì)原料水蒸汽配氫氣合計(jì)工業(yè)氫二氧化碳或PSA廢氣排出凝水工業(yè)氫二氧化碳或PSA廢氣排出凝水噸/年噸/年噸/年噸/年%噸/年噸/年噸/年%合計(jì)100619144515603705.218.3781.260.07370388.63736299.22904791.236.7613.4453.03上市999588.9544105583328.218.4181.230.06368935.63726174.22868387.236.7913.3752.83非上市66024100237713.7685.450.79

34、1453.0010125.0036404.003.0321.1075.871燕山 ()3985711620333615639325.4874.300.22100.0010448.0028753.00117195.006.6818.3974.94 ()9037142320952994317.0579.863.09100.0031524.00258132.005.9548.712天津 ()22509100.008641.001156.003石家莊153986304.009043.0040.9458.730.004滄州 5270.9553324593.259188.158.990.091.00100

35、.002081.616167.004987.593.5210.428.435齊魯 ()5978337777648043803913.6586.240.11100.0021527.0045100.00208000.004.9110.3047.48 ()7736348886471756694413.6486.230.13100.0028796.0025336.00296500.005.084.4752.306勝石化727954470756182411.7788.100.13100.002178.0028358.0031288.003.5245.8750.617金陵 ()18008116726013

36、473413.3786.630.00100.0010058.0048621.6076054.407.4736.0956.458揚(yáng)子 7137450502161357700821820.0049772.003.788.639武漢 ()187614909.0013537.0010 荊門(mén) 209801448002016580012.6587.330.02100.0013178.0053688.0098934.007.9532.3859.6711 長(zhǎng)嶺 12744537611636666835.350.284903.0037376.307.350.0056.0612 高橋 ()143868617001

37、0055614.3185.690.00100.005027.0024662.0070455.005.0024.5370.07 ()28723150017017874016.0783.930.00100.009926.0049621.00118072.005.5527.7666.06369續(xù)表4序號(hào)廠名(裝置簡(jiǎn)稱(chēng))進(jìn)料量百分率出料量產(chǎn)品產(chǎn)率原料水蒸汽配氫氣合計(jì)原料水蒸汽配氫氣合計(jì)工業(yè)氫二氧化碳或PSA廢氣排出凝水工業(yè)氫二氧化碳或PSA廢氣排出凝水噸/年噸/年噸/年噸/年%噸/年噸/年噸/年% ()2849816188219038014.9785.03100.008449.0038770.0014

38、2939.004.4420.3675.0813 上海石化()8319325021416.00 ()61824208400027022422.8877.120.00100.0020609.5919445.00119968.007.637.2044.4014 鎮(zhèn)海 ()37381757402131229.8970.11100.001920.008455.3610936.569.0139.6751.32 ()23356143566.01016692213.9986.010.00100.0012334.0059346.22146519.477.3935.5587.7815 廣州 ()592582316

39、991029096720.3779.630.00100.0019497.1752653.15218816.586.7018.1075.20 ()958793950211049091119.5380.470.00100.0046844.0047889.00396177.609.549.7680.7016 茂名 ()5523523816729340218.8381.17100.0029459.0022642.00128650.0010.047.7243.8517 杭州 6602410023774798113.7685.450.79100.001453.0010125.0036404.003.032

40、1.1075.8718 塔河 1650961548617811821.1378.790.08100.005680.9932690.1939746.737.2741.8550.8819 海南 43219248054029127314.8485.160.00100.0013342.2750181.68205610.004.5817.2370.5920 青島煉化26073134306016037916.2583.750.00100.008063.0010287.00142029.005.036.4188.56370五、主要技術(shù)經(jīng)濟(jì)指標(biāo)表5序號(hào)廠名(裝置簡(jiǎn)稱(chēng))輕油動(dòng)力消耗能耗催化劑消耗現(xiàn)金操作費(fèi)用單位

41、加工費(fèi)含油污水含油排污合格率非計(jì)劃停工餾出口合格率上報(bào)事故電蒸汽工業(yè)凈水(新鮮水)循環(huán)水脫鹽水燃料氣總天數(shù) 總次數(shù)t/km3kw.h/km3t/km3t/km3t/km3t/km3kg/km3千克標(biāo)油/千米3kg/km3元/噸元/噸mg/l%天次%次合計(jì)0.3856.70-0.170.0511.932.29126.14127.730.2715.999.9685699.791上市0.3856.86-0.170.0511.932.29126.64127.730.2716.699.9585699.781非上市21.0010.00125.000.000.01000010001燕山 ()11.99-0.

42、150.001.222.2882.190.01000095.780 ()59.08-0.630.004.28141.8198.900.000.11001110012天津 ()56.200.140.1834.320.00118.5065.0820.01000099.1803石家莊13.18-25.090.002.834.2586.0481.174.179.299.000099.9704滄州 192.1410.85111.35184.68100.010081410005齊魯 ()0.0369.42-0.030.002.432.16171.56141.790.10001000 ()1.76100.001.520.0015.601.77105.50103.600.070010006勝石化2