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CarbonCaptureandSequestration(SalesPitch)AlexanderVoice24November2019CarbonCaptureandSequestrati1OverviewMotivationforthedevelopmentofCCStechnologyClimatechangeEnergyprofileandoutlookPublicperceptionofCCSCCStechnologicaloverviewCCSchallengesandsolutionsOverviewMotivationforthedev2MuirGlacier,August,1941MuirGlacier,August,19413MuirGlacier,August,2019MuirGlacier,August,20194ClimateChange

CO2–TemperatureCorrelationSource:Petitet.al.

,Nature,2000ClimateChange

CO2–Temperatu5ClimateChange

PredictingGlobalTemperatureIncreasesSource:IPCCReportonClimateChange,2019Averageglobaltemperatureshaverisen.75°Cinthepast100years.Howmuchwilltheriseinthenext100years?ClimateChange

PredictingGlob6ClimateChange

PredictedImpactSource:SternReviewontheEconomicsofClimateChange,2019ClimateChange

PredictedImpac7ClimateChange

PredictedImpactClimateChange

PredictedImpac8ClimateChange

ConclusionsCO2concentrationhighestinlast650,000yearsWarmingoftheclimatesystemisunequivocal,mostoftheglobalwarmingofthepasthalf-centuryisduetoincreasesingreenhousegasesGlobalGHGemissionsreductionchallengeStabilizeCO2(e)

concentrationsat450ppm(2.0–2.4°Ctemperaturerise)PeakCO2concentrationbefore2019Reduce2050emissionsto50-85%of2000emissionsReduceannualglobalemissionsto5GtlongtermClimateChange

ConclusionsCO29PublicSupport

forCCSMITCarbonSequestrationInitiative,Survey,2019PublicSupport

forCCSMITCar10WhyweneedCCS

USEnergyProfileGlobalCarbonDioxideEmissionsfromElectricityin2019Total=10,539MtGlobalCO2PSEmissions2019Total=13,375Mt(60%oftotal)WhyweneedCCS

USEnergyProf11WhyweneedCCS

EnergyOutlookSource:EIA,InternationalEnergyOutlook,2019YearQuad.BTUOilCoalNGNuclearRenewablesWhyweneedCCS

EnergyOutlook12WhyweneedCCS

EmissionsMitigationPotentialSource:IPCCSpecialReportonCarbonCaptureandSequestrationWhyweneedCCS

EmissionsMiti13CCSOverviewCapturePowerplantsNGtreatmentOilrefineriesTransportationPipelinesShipsSequestrationGeologicalformations(underground)OceanWhatisthescaleofthisproject?800GWCoal/1600GWNG1GtCO2/1BSCFDCCSOverviewCapture800GWCoal14CarbonCaptureOptions

TechnologiesOverviewSystemsPost-combustionPre-combustionOxy-fuelIndustrialprocesses(e.g.NGsweetening)SeparationtechnologiesSolvents–aqueousaminesandsaltsMembranes–polymericSolidsorbents–Lime,zeolite,activatedcarbonCryogenicprocesses–Liquefaction/distillationCarbonCaptureOptions

Technol15CarbonCaptureOptions

Post-CombustionSource:co2crc.au/ABSSTRPHXRecirculating(amine)solventCO2CleangasFluegasCarbonCaptureOptions

Post-Co16Absorption/Stripping

TechnicalDiagramABS40°CSTRP120°CHXRecirculating(amine)solventENERGYCO2CleangasFluegasAbsorption/Stripping

Technic17Absorption/Stripping

ProcessDetailsCO2+OH-C2H4-NH2+B OH-C2H4-NH-CO2+BH+HeatAbsorptionofCO2byMEAat40°CMEArecoverybydesorptionat120°CReboilerprovidesheattodesorberintheformofsteamfromtheboiler,reducingplantoutputandefficiencyOptimizeloading,operatingtemperature,minimizesolventlossesAbsorption/Stripping

Process18Absorption/Stripping

TechnicalChallengesandSolutionsFormationofheatstablesaltsprecipitationtoproducefertilizerCorrosionofequipmentbyaminesolventadditionofCu2+orVa4+tosolutionDegradationofsolventadditionofEDTAorotherinhibitortosolutionEnergyusesolventstorage/cycling;useofsalts,highpressureprocesses,newsolventsAbsorption/Stripping

Technic19CarbonCaptureOptions

Oxy-FuelProcessSource:co2crc.au/CarbonCaptureOptions

Oxy-Fue20CarbonCaptureOptions

Pre-CombustionSource:co2crc.au/CarbonCaptureOptions

Pre-Com21CarbonTransport2500kmofpipeline/50Mtyr-1inwesternUSTODAYUseofexistinginfrastructure–requiredry,sweetgastopreventcorrosionChallengesaremanageable,similartotransportofhydrocarbonsCarbonTransport2500kmofpipe22CarbonSequestrationBigpicture–Storageinoilreservoirs(depletedandEOR),naturalformations,oceanstorageWillitleak?Notlikely–modelssuggest99%containmentExistingreservoirdatacanbeusedtoestimatestoragepotentialandaddress(water)concernsNogroundwatercontamination(salt?)CarbonSequestrationBigpictur23AnswersAnswers24謝謝!謝謝!25CarbonCaptureandSequestration(SalesPitch)AlexanderVoice24November2019CarbonCaptureandSequestrati26OverviewMotivationforthedevelopmentofCCStechnologyClimatechangeEnergyprofileandoutlookPublicperceptionofCCSCCStechnologicaloverviewCCSchallengesandsolutionsOverviewMotivationforthedev27MuirGlacier,August,1941MuirGlacier,August,194128MuirGlacier,August,2019MuirGlacier,August,201929ClimateChange

CO2–TemperatureCorrelationSource:Petitet.al.

,Nature,2000ClimateChange

CO2–Temperatu30ClimateChange

PredictingGlobalTemperatureIncreasesSource:IPCCReportonClimateChange,2019Averageglobaltemperatureshaverisen.75°Cinthepast100years.Howmuchwilltheriseinthenext100years?ClimateChange

PredictingGlob31ClimateChange

PredictedImpactSource:SternReviewontheEconomicsofClimateChange,2019ClimateChange

PredictedImpac32ClimateChange

PredictedImpactClimateChange

PredictedImpac33ClimateChange

ConclusionsCO2concentrationhighestinlast650,000yearsWarmingoftheclimatesystemisunequivocal,mostoftheglobalwarmingofthepasthalf-centuryisduetoincreasesingreenhousegasesGlobalGHGemissionsreductionchallengeStabilizeCO2(e)

concentrationsat450ppm(2.0–2.4°Ctemperaturerise)PeakCO2concentrationbefore2019Reduce2050emissionsto50-85%of2000emissionsReduceannualglobalemissionsto5GtlongtermClimateChange

ConclusionsCO234PublicSupport

forCCSMITCarbonSequestrationInitiative,Survey,2019PublicSupport

forCCSMITCar35WhyweneedCCS

USEnergyProfileGlobalCarbonDioxideEmissionsfromElectricityin2019Total=10,539MtGlobalCO2PSEmissions2019Total=13,375Mt(60%oftotal)WhyweneedCCS

USEnergyProf36WhyweneedCCS

EnergyOutlookSource:EIA,InternationalEnergyOutlook,2019YearQuad.BTUOilCoalNGNuclearRenewablesWhyweneedCCS

EnergyOutlook37WhyweneedCCS

EmissionsMitigationPotentialSource:IPCCSpecialReportonCarbonCaptureandSequestrationWhyweneedCCS

EmissionsMiti38CCSOverviewCapturePowerplantsNGtreatmentOilrefineriesTransportationPipelinesShipsSequestrationGeologicalformations(underground)OceanWhatisthescaleofthisproject?800GWCoal/1600GWNG1GtCO2/1BSCFDCCSOverviewCapture800GWCoal39CarbonCaptureOptions

TechnologiesOverviewSystemsPost-combustionPre-combustionOxy-fuelIndustrialprocesses(e.g.NGsweetening)SeparationtechnologiesSolvents–aqueousaminesandsaltsMembranes–polymericSolidsorbents–Lime,zeolite,activatedcarbonCryogenicprocesses–Liquefaction/distillationCarbonCaptureOptions

Technol40CarbonCaptureOptions

Post-CombustionSource:co2crc.au/ABSSTRPHXRecirculating(amine)solventCO2CleangasFluegasCarbonCaptureOptions

Post-Co41Absorption/Stripping

TechnicalDiagramABS40°CSTRP120°CHXRecirculating(amine)solventENERGYCO2CleangasFluegasAbsorption/Stripping

Technic42Absorption/Stripping

ProcessDetailsCO2+OH-C2H4-NH2+B OH-C2H4-NH-CO2+BH+HeatAbsorptionofCO2byMEAat40°CMEArecoverybydesorptionat120°CReboilerprovidesheattodesorberintheformofsteamfromtheboiler,reducingplantoutputandefficiencyOptimizeloading,operatingtemperature,minimizesolventlossesAbsorption/Stripping

Process43Absorption/Stripping

TechnicalChallengesandSolutionsFormationofheatstablesaltsprecipitationtoproducefertilizerCorrosionofequipmentbyaminesolventadditionofCu2+orVa4+tosolutionDegradationofsolventadditionofEDTAorotherinhibitortosolutio

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