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UNITEDNATIONSCONFERENCEONTRADEANDDEVELOPMENT
Technicalcooperationoutcome ADVANCECOPY
Leavingtheshore
Marine-basedsubstitutesandalternativestoplastics
Geneva,2025
?2025,UnitedNationsConferenceonTradeandDevelopment
Thefindings,interpretationsandconclusionsexpressedhereinarethoseoftheauthorsanddonotnecessarilyreflecttheviewsoftheUnitedNationsoritsofficialsorMemberStates.
ThedesignationsemployedandthepresentationofmaterialonanymapinthisworkdonotimplytheexpressionofanyopinionwhatsoeveronthepartoftheUnitedNationsconcerningthelegalstatusofanycountry,territory,cityorareaorofitsauthorities,orconcerningthedelimitationofitsfrontiersorboundaries.
MentionofanyfirmorlicensedprocessdoesnotimplytheendorsementoftheUnitedNations.Photocopiesandreproductionsofexcerptsareallowedwithpropercredits.
Thispublicationhasnotbeenformallyedited.
UNCTAD/TCS/DITC/INF/2025/4(advancecopy)
Leavingtheshore
Marine-basedsubstitutesandalternativestoplastics
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iii
Acknowledgements
ThisstudywaspreparedbytheDivisiononInternationalTradeandCommoditiesofUNTradeandDevelopment(UNCTAD),underthesupervisionandguidanceofChantalLineCarpentier,HeadoftheTrade,Environment,ClimateChangeandSustainableDevelopmentBranch.DavidVivas-EuguiandHenriquePaciniofUNCTADledthestudyteam.
UNCTADgratefullyacknowledgesthesubstantivecontributionsofLorenzoFormenti(UNCTADconsultant),KatnissXuejiaoLi(UNCTADvisitingresearcher)andMalickKane(UNCTAD)inthepreparationoftheoverallstudy.ThetechnicalinputsofRachidAmui(UNCTAD),ElisabettaErba(UniversitàdegliStudidiMilano),andPatriziaSilva(environmentalbiologist)inthewritingofchapter2;SaraFerro(sustainabilityexpert)andMariaDurleva(UNCTADconsultant)inthewritingofchapter3;MarcoFugazza,ChristianKnebel,LalenLleanderandSamuelMunyaneza(UNCTAD)inthewritingofchapter4arealsogratefullyacknowledged.
ThestudybenefitedfrominterviewswithBhimaAriesDiyanto(Reciki),AzzedineBadis(SeaweedCoalition),CindyParokkil(InternationalOrganizationforStandardization,ISO),CraigUpdyke(AmericanSocietyforTestingandMaterials,ASTM),JuliaReisser(Uluu),MalihaSumar(TheFlipFlopi/ThePeople&PlanetCompany),NurAhyani(WorldWildlifeFund-,WWF),XuesongLiu(Bottloop),SamanthaKiernan(YaleUniversity),MaheshSughatan(ForumonTrade,Environment,andtheSDGs),ShuntaYamaguchi(OrganisationforEconomicCo-operationandDevelopment,OECD).
ThisstudyresultsfromthecooperationbetweentheSustainableManufacturingandEnvironmentalPollution(SMEP)andOceanEconomyandFisheriesProgrammesofUNCTAD,withthesupportoftheForeign,CommonwealthandDevelopmentOffice(FCDO)oftheUnitedKingdomofGreatBritainandNorthernIrelandandtheGovernmentofPortugal.
DesktopformattingwasdonebyRafeDent(UNCTAD)andLiaTostes(UNCTADconsultant).
Abbreviations
ABS accessandbenefit-sharing
ASC AquacultureStewardshipCouncil
ASTM AmericanSocietyforTestingandMaterials
AVE ad-valoremequivalents
CAGR compoundannualgrowthrate
CITES ConventiononInternationalTradeinEndangeredSpeciesofWildFaunaandFlora
CSOs civilsocietyorganizations
FTA Freetradeagreement
GSC GlobalSeaweedCoalition
HS HarmonizedCommodityDescriptionandCodingSystem
ISA InternationalSeabedAuthority
KIIs keyinformantinterviews
LCA lifecycleassessment
MBSAs marine-basednon-plasticsubstitutesandalternatives
MEAs multilateralenvironmentalagreements
MFN mostfavourednation
MSC MarineStewardshipCouncil
NTMs non-tariffmeasures
P&C PrinciplesandCriteria(ofUNCTADBioTrade)
PE polyethylene
PHAs polyhydroxyalkanoates
PPMs processandproductionmethods
PS polystyrene
SIDS SmallIslandDevelopingStates
SMEP SustainableManufacturingandEnvironmentalPollutionProgramme
SPS sanitaryandphytosanitary(measures)
TBT technicalbarrierstotrade
TrPMs trade-relatedpolicymeasures
TüV Technischerüberwachungsverein(TechnicalInspectionAssociation)
VSS voluntarysustainabilitystandards
WCO WorldCustomsOrganization
WIPO WorldIntellectualPropertyOrganization
WTO WorldTradeOrganization
WWF WorldWildlifeFund
Tableofcontents
Executivesummary 1
ChapterI
Introduction 6
ChapterII
Marine-basednon-plasticsubstitutesandalternatives(MBSAs).9
Thepotentialofmarineresourcestoreplaceplastics 11
Afirstglobalmapping 13
ChapterIII
Challengesandopportunitiesforsustainablesocio-economic
development 15
Opportunitiesandenablingfactors 17
Seaweedandalgae 18
Marineminerals 20
Marineinvertebrates,plantsandwaste 22
Barrierstomarketdevelopment 22
Marketdynamics 23
Enablingtechnologyandinfrastructure 24
Socialandenvironmentalgovernance 27
EnvironmentalimpactthroughLCA 34
Theconventionalwisdomandlifecyclethinking 34
Keysubstitutiontradeoffs 35
ChapterIV
PursuingMBSAsthroughatradelens 39
4.1TheHarmonizedSystem(HS)asaframeworkformeasuring
tradeinMBSAs 41
TrendsandprospectsinglobalMBSAtrade 44
Globaltradetrends 44
MarketaccesspoliciesappliedtoMBSAs 48
ImporttariffsappliedtoMBSAs 48
Non-tariffmeasuresappliedtoMBSAs 50
ChapterV
Conclusionandthewayforward 56
References
62
Annex1 71
Annex2 72
Annex3 76
Annex4 78
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Executivesummary
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3
Executivesummary
Plasticpollutionthreatensmarineecosystems,humanhealth,andeconomicdevelopment.Theexcessiveuseofplastics,coupledwithinadequatewastemanagementsystems,hasledtotheaccumulationofplasticdebrisandplasticparticlesinoceans,posingriskstomarinelifeandcoastalcommunities.
Inresponsetothisgrowingcrisis,aUnitedNationsGlobalPlasticsTreatyisundernegotiations.UNCTADhasbeenconductingresearchandadvocatingfortherecognitionofnon-plasticsubstitutesandalternativesinthefuturetreaty.
Thisreportbuildsonpreviousresearchandexplorestheroleofmarine-basednon-plasticsubstitutesandalternatives(MBSAs).Thesealternatives,derivedfrommarineresourcessuchasseaweed,algae,andmarineminerals,offerpotentialtoreplaceconventionalplasticsinvariousapplications,therebyreducingplasticwasteandsupportingsustainabledevelopment.Unlikeconventionalplastics,MBSAsareofnaturalorigin,rangingfromalgae-basedpolymersforbioplasticstomineralcompounds
usedasfillersinglassandceramics.
Usingamixed-methodsapproachcombiningdeskresearch,originaldataanalysis,andkeyinformantinterviews(KIIs)(seeAnnex1),thisstudyinvestigatestheeconomicfeasibility,benefits,andtradeimplicationsofMBSAs,emphasizingtheirdualroleinmitigatingplasticpollutionandpromotingsocioeconomicdevelopment,particularlyincoastalregionsand
SmallIslandDevelopingStates(SIDS).ItalsoidentifiesanddiscusseskeychallengesrelatedtothedevelopmentofglobalMBSAindustriesinallthreedimensionsofsustainabledevelopment:economic,social,andenvironmental,assessingthematurityandoverallfitnessofenablingpolicyframeworks.
Inprinciple,marine-basedmaterialscanbeviablealternativestofossilfuel-basedplasticsduetotheirbiodegradability,goodfunctionality(e.g.,strength,flexibility)andrelativelylowenvironmentalfootprint.
Theirwidespreaduseinsupplychains,suchaspackaging,couldsignificantlyreduceplasticwasteanditsnegativeimpactonthemarineenvironment.Theglobalcommitmenttosustainabilityandthepotentialofmarinenaturalcapitaltosupporttransitionstoenvironmentallyfriendly,equitableandinclusiveproduction
systemsarealsoenablingMBSAs.However,well-documentedrisksassociatedwithmarineresourceexploitation–suchasthedepletionofhabitats,oceanacidification
andchemicalpollution,includingfromunregulatedorintrusiveseabedmining
–requirecarefulconsideration.
ByreviewingcasestudiesofsuccessfulMBSAimplementationworldwide,
thestudydemonstratesthatMBSAs,suchasalgae-basedbiopolymers,canreplaceconventionalplasticsinvariousofapplications,includingbutnotlimitedtopackagingandtextiles.Inthisview,thefurtherdevelopmentandmarketuptakeofMBSAscanalsoaddvaluetoupstreamoceanindustries,suchasseaweedfarming.Weassesspracticalviability
andmarketpotentialprovidingabasisforfurtherpolicyandanalyticalwork.
UNCTAD
advocatesfortherecognition
ofnon-plasticsubstitutesandalternativesinthefuture
GlobalPlasticsTreaty
GlobalMBSA
exportsreached$10.8billionin2022,growingthreetimesfasterthansynthetic
polymersoverthepast
decade
Thesocio-economicbenefitsofMBSAstypicallyincludejobcreation,economicdiversificationandimprovedlivelihoods,particularlyforyouthandwomen,aswellasfosteringindigenousinnovation,resiliencetoeconomicshocks,andfoodsecurity.Challengesinvolvetheneedfortechnologicalinnovationanddiffusion,sustainableharvestingpractices,and
marketaccess.Atpresent,highcostsandunfavourableeconomicshindermarketdevelopmentinseverallocations.Robustsupplychainsneedtobeestablished,withtargetedinvestmentsinresearchand
developmentandpublic-privatepartnershipstosupportthegrowthoftheMBSAsector.
SustainabilityisalsoakeydriverforthedevelopmentofMBSAindustries,requiringpolicyframeworksthatenablefairsupplychainrelationshipsandsoundnaturalresourcemanagement.Inthiscontext,lifecycleassessment(LCA)isimportanttoensurethattheenvironmentalbenefitsofMBSAs,suchasthelowcarbonfootprintinproduction,arenotoffsetbynegativeimpactsatotherstagesoftheirlifecycle.Thisisthecasewithmarinebioplastics,whichcanreleasegreenhousegases(GHGs)duringdecompositionintheabsenceofindustrialcompostingfacilities.
BilateraltradeflowdatashowthattheglobalmarketforMBSAsisgrowingwithsignificantpotentialforexpansion.Aftergrowingthreetimesfasterthansyntheticpolymersexportsbetween2012and2022,globalMBSAexportsreached
$10.8billionin2022.Theparticipationofcoastaldevelopingcountriesinthismarkethasalsoincreasedovertime,withsomebecomingtradingpowerhousesforcertainproducts(e.g.,Indonesiaforseaweed).
However,tariffsandnon-tariffmeasures(NTMs),includingenvironmental,healthandsafetyrequirements,hindermarketaccessforthesematerials,especiallyindevelopingcountries.Exceptformarineminerals,allMBSAsaresubjecttohighertariffsandmorestringentNTMsthanconventionalplastics.Sanitaryandphytosanitary(SPS)measureslinkedto
theirtradecanresultinhighcompliancecostsforcompanies.Thisisthecaseofseaweed,wherehealthrulesforedibleproductsalsoapplytonon-foodmaterialsusedinpackaging.ReducingtradebarriersandharmonizingrulescanenhancetheglobalcompetitivenessofMBSAs,suchasthroughmultilateraltradeandenvironmentalagreementsandstandard-settinginitiatives.
Inmovingforward,multi-stakeholderandinternationalcooperationisessentialtoaddressthesechallengesandfullyunlockthepotentialofMBSAs.Thesematerialsofferaviablestrategyfortacklingplasticpollutionwhilepromotingsustainableandinclusiveeconomic
developmentthroughtrade,especiallyfordevelopingcountries.Thepotentialrolesofstakeholdersinthisregardinclude:
Intergovernmentalorganisations(IGOs)andtheirmembers:considertheincorporationofanenablinginnovationandregulatorycontrolsmechanismforMBSAsandothernon-plasticsubstitutesundertheongoingUnitedNationsnegotiationsforaninternationallegallybindinginstrument(ILBI)onplasticpollution,includinginthemarineenvironment,creatingalevelplayingfieldwithplasticproducts.TheWorldCustomsOrganization(WCO)couldenhancetradeflowaccuracybyassigningdetailedcodesforMBSAs.AUnitedNationsTaskForceonseaweedcouldsupport
R&Dandregulatorydiscussions.
Governments:Establishsupportiveregulatoryframeworks,economicincentives,andpublic-privatepartnershipstoenableMBSAmarkets.Additionally,collaborateinR&DtoacceleratetheadoptionofMBSA.
Businesses:SupportsupplychainandmarketdevelopmentthroughR&Dinvestment,either
independentlyorinpartnershipwithgovernments;investinMBSA;adoptsustainablesourcingpractices,andadvocateforfavourablepolicies.
CivilSociety:Raiseawarenessthroughcampaignsandcommunityprojects,sensitizingstakeholdersandholdinggovernmentsandcompaniesaccountablefortheirsustainabilitycommitments.
Academia:EnhanceunderstandingoftherisksandopportunitiesassociatedwithMBSAsthroughcomprehensive,interdisciplinaryresearchandhelpdevelopmarket-readysolutionstoadvanceMBSAs.
Consumers:FostermarketgrowthanddriveadoptionofMBSAsbymitigatingcostbarriersandcultivatingenvironmentalawarenessandawillingnesstopayforsustainable
blueeconomyalternatives.
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Marine-basedsubstitutesandalternativestoplastics
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ChapterI
Introduction
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Introduction
Plasticshavebecomeafundamentalenablerofhumaneconomicactivityasitisinextricablywovenintothefabricoftheglobaleconomyandtrade.Theirlowcostandunparalleledversatilityhavedriventheirwidespreadadoptionacrossallsectors,fromconsumergoodstoindustrialapplications,leadingtheworldtobeundeniablyplastic-dependent.Tradeinplasticsatalllevelsofthevaluechainalreadyreachedarecord$1.2trillionin2022(UNCTAD,2023a).Projectionsdonotshowadifferentoutlook.Withoutdecisivepolicyinterventions,plasticuseisonatrajectorytotripleby2060,withthelargestincreasesexpectedindevelopingregionssuchasSub-SaharanAfricaandAsia(OECD,2022).
Whileplasticshavebeeninstrumentaltoeconomicgrowth,theyhavealsoemergedasanunprecedentedthreatto
theenvironmentandhumanhealthduetotheirpersistentnature.Intheabsenceofcertainconditions,plasticswastecantakebetween20toover500yearstobreakdownanddegradeintheenvironment,dependingonthechemicalcompositionandtheproduct(UnitedNations,2021).
Ineffectivewastemanagementacrosstheglobehasexacerbatedthiscrisis,leadingtoapervasivepollutionproblem.Frommunicipalsolidwastetomicroplasticspollutingtheocean,theenvironmentalandhealthconsequencesareprofound.Despiteglobalefforts,plasticwasteisexpectedtopermeateecosystemsfor
decadestocome(Winnie,Lauetal.,2020).
Thealarmingglobalissueofplasticspollutionhascreateda“pressingcase”fornaturalandenvironmentallyfriendlysubstitutesandalternativestoplastics(UNCTAD,2023a).Whilephasingoutplasticsentirelymaynotbefeasibleintheshortterm,developingandadoptingalternativematerialscouldplayacrucialroleincurbingplasticwaste.Inthisviewthatcountriesarebeingencouragedto
transitiontowardsanewplasticseconomythatreducepollutingplasticuseandprioritizes,wherepossible,sustainableandsafesubstituteswithcomparablefunctionalproperties.Traditionalmaterials,suchas
paperandglass,offerestablishedandreadilyavailableoptionsforreducingourrelianceonplastics.Innovativeapproacheshavescaledwheresubstitutessuchaspaperandglassworkalongsideplastics
tocreatesustainableproducts.Forinstance,flexiblepackaging,combinespaperandplasticfilmofferingtoprovidefunctionality(e.g.,moistureinsulation)thatiscomparabletothatofplastic-basedsolutions.Atthesametime,lesscommonfibre-basedmaterials,suchasbagasseandbamboo,aregainingtractionasarenewableandbiodegradablealternativesforsingle-useplasticproducts(e.g.,cups,straws),promotingacirculareconomy
byaddingvaluetoexcessbiomass.
Whiletheirscalabilityisstilluncertain,theirpotentialisbeingexploredbymaterialsscientistsandsustainabilityexperts,pavingthewayfornewbusinessmodelsthatcombinevalueadditionandresourceefficiency.UNCTADresearchshowsthatnon-plasticsubstitutesandalternativesareattractingmoreregulatoryinterest
asbusinessesincreasinglyrecognizethebenefitsofsustainability.Indeed,sustainabletradecannotonlysupportthediffusionoflowcarbonmaterialsand
technologiesbutalsocontributetosocio-economicdevelopmentinproducingcountries.However,tofullyrealizethispotential,investmentmustberedirectedfromfossilfuel-basedplasticproduction
towardsnewbusinessmodelscentredonsubstitutematerials(ThePewCharitableTrustsandSYSTEMIQ,2020).
Marineandcoastalecosystemsareincreasinglyrecognizedaspivotalforthesustainabledevelopmentofcoastalregions,particularlySIDS.Theiruniquenaturalcapitalprovidesaprimeopportunitytofosternewentrepreneurialecosystemsthatcanbalanceeconomicgrowthwithenvironmentalprotection,throughtrade.Ecosystems,
suchasfarming,processingandmarketingofalgalproducts,offerpotentialaccess
tonaturalresources(e.g.,water,minerals)withreducedcompetitionandlandusepressures.However,challengessuch
astheconservationofbiodiversityandmarinehabitatsmustbecarefullymanagedthrougheffectivepolicyframeworksto
fullyrealizethepotentialbenefits.
Thisstudypresentsoriginalresearchdemonstratingthepotentialfortradeinmarine-basednon-plasticsubstitutesandalternatives(MBSAs)toaddressplasticpollution,whilepromotingsustainableeconomicdevelopmentincoastalcommunities,includinginSIDS.Bylookingatselectedocean-basedsupplychainsandunconventionalusesoftheirproductsandbyproducts,suchastheproduction
ofbioplasticpolymersfromalgae,itrespondstothreespecificobjectives:
IdentifypromisingMBSAs,definedasnaturalresources,bio-basedmaterialsandcomponentsthathavearoleorpotentialinreplacingfossilfuel-basedplastics,eitherdirectly,asbuildingblocksoradditivesforalternativebioplastics,orindirectly,asinputstoproducenon-plasticsubstitutes(e.g.,ceramics,glass).
Analysethepotentialfortrade-ledsocio-economicdevelopmentofMBSAsinproducingcountriesvis-à-visenvironmentalandsocialrisks.
Accordingly,discussthemaintrade-offsbetweenenvironmentalsustainabilityandeconomicfeasibilityassessedthroughLCAconsiderations.
Discusspolicyframeworksthatcanincentivizetradeinmarine-basednon-plasticsubstitutesand
alternatives,includinge.g.,tariffandnon-tariffmeasures,andstandards.ThisisintendedtoinformtheupcomingroundsofnegotiationsofaUnitedNationsGlobalPlasticsTreaty,withaviewtosupporttrade-relatedpolicycoherenceandharmonization.
Chapter1providescontextandintroducestheoverallpurposeandobjectivesofthestudy,includinganoverviewofmarinebiomaterialsandtheirdownstreamuses.Chapter2highlightstheirpotentialforsustainabletradeandpresentsanovelmappingofMBSAscoveringmarineresourcesandtheirimmediatederivatives.
Chapters3and4examinethemicro-economicsandlocalimpactsofglobalMBSAtrade.Chapter3discussesthemainchallengesandopportunitiesforsocio-economicdevelopmentaffectingMBSAindustries.OpportunitiesareanalysedforkeyMBSAsupplychains,suchasseaweedandalgae,whilethreemaintypesofbarrierstothedevelopmentoftheseindustries
areconsidered:marketdynamics(e.g.,economiesofscale),enablingtechnologiesandinfrastructure,andsustainability.
Thechapteralsomapsoutthemainenvironmentalimpactsoriginatingfromtheproduction,marketing,consumptionanddisposalofMBSAsanduseslifecycle
thinkingtodiscussthemaintrade-offsinthesubstitutionformoresustainablematerials.
Fromatradeperspective,Chapter4estimatesthesizeoftheglobalMBSAmarketusingbilateraltradeflowdataasaproxyfordemand.Theaverageappliedtariffsandnon-tariffmeasures(NTMs)
affectingthesematerialsarealsoanalysedtoprofilethetradedistortionsandmarketaccessconditionsprevailinginMBSAmarkets.Chapter5concludesandprovidesanarrativeonthewayforward.
Plasticwastecantakebetween
20toover
500yearstodegradeintheenvironment
Leavingtheshore
Marine-basedsubstitutesandalternativestoplastics
9
ChapterII
Marine-basednon-plastic
substitutesandalternatives
(MBSAs)
Leavingtheshore
Marine-basedsubstitutesandalternativestoplastics
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Leavingtheshore
Marine-basedsubstitutesandalternativestoplastics
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11
Marine-basednon-plasticsubstitutesandalternatives(MBSAs)
Theocean
offersunderexploredopportunitiestocurbplasticwastethroughmarine-basedsubstitutes
Thepotentialofmarineresourcestoreplaceplastics
Throughitsuniquemixofnaturalcapital,theoceanhasshapedthecourseofhumanhistoryanddeterminedthekeytrajectoriesofcivilization.Fromensuringsustainablelivelihoodsthroughfisheriestofacilitatingtraderoutes,humanityhaslongreliedonoceanstomeetitsmostpressingeconomicandsocialneeds(Allisonet
al.2023).Astheworldisconfrontedwiththeneedtotransitiontomoreequitableandsustainableproductionsystems,
theoceancontinuestoprovideaccesstoinvaluableresourcesandecosystem
services,suchascarbonsequestrationandbiodiversityconservation,withincreasinginterestfromgovernmentsinpromoting
itforthedevelopmentoftheirnationaleconomies(Martínez-Vázquez,Milán-GarcíaanddePabloValenciano,2021).
However,theoceanisnotimmunetothenegativeenvironmentalexternalitiesofhumanactivityandthechallenges
ofachangingclimate(IPCC,2019andIOC-UNESCO,2022).Duetothenon-biodegradablenatureofconventionalplastics,plasticpollutionhasbecomeasignificantthreattomarineecosystemsandcoastalcommunities.1
Theveryenvironmentthreatenedbyplasticsmightofferpreviouslyunderexploredopportunitiestocurbplasticwaste
andholdthekeytoamoresustainablefuture.Infact,manyofthebio-basedcomponentsthatcanreplacefossilfuel-basedplastics,suchasinfoodpackaging,haveastrongmarineconnectionandcanbesourcedfromthemarineandcoastalenvironment(Ayyakkalaietal.,2024;Pipunietal.,2023;Boseet.Al,2023).
MBSAsencompasstheentiremateriallifecycle,fromrawmaterialextractiontoend-of-life.Theyrangefromlivingorganismsfoundinmarineandcoastalecosystemsthatcanbeusedasfeedstock(e.g.,seaweed)toby-productsofaquacultureorseafoodprocessingassourcesof
biologicalcompounds(e.g.,molluscshells).
Thepotentialapplicationsforreplacingplasticsarediverseandvaryaccordingtotheirdegreeofconversion(Table
Forinstance,microalgaeandothermicroorganismsshowstrongpotentialasasourceofbiopolymers,suchaspolyhydroxyalkanoates(PHAs),whicharedirectlyusedasbuildingblocksforbioplastics.2Conversely,inorganic
compoundssuchasmineralscanindirectlysupportthesubstitutionofplasticsasinputstoproducenon-plasticsubstitutes.Forexample,highpuritysilicasandshavewideapplicationsintheproductionofglass.
Contrarytopopularbelief,biodegradableplasticsarenotapanaceaforplasticpollution.Theyonlydegradeunderspecificconditionsandtheirrateofdegradationinthenaturalenvironmentcanvarysignificantlydependingonhowwelltheseconditionsaremet.Influencingfactorsincludethetypeofbioplastics,environmentalconditions(e.g.,temperature,humidity,availabilityofoxygen)andthepresenceofmicroorganismsthataffectdegradation.Whilebiodegradableplasticscandegradeintheocean,theymaytakealongtimetodegradeormaynotbreakdowncompletelyintoharmlesssubstancesduetofactorssuchassalinityandpollutants.Theseconsiderationsalsoapplytomarine-basedbioplastics.
Technically,polymersarelargemoleculesformedbylinkingnumeroussmallermolecules,calledmonomers,throughcovalentchemicalbonds.Thesemonomersactasrepeatingunits,creatingalongchain-likestructure.Thespecificpropertiesofapolymer(strength,flexibility,etc.)aredeterminedbythetypeofmonomerused,thelengthofthechain,andthearrangementofthemonomerswithinthechain.Theseuniquepropertiesallowpolymerstobethefundamentalbuildingblocksofplastics.Byvaryingthemonomerandchainstructure,avastarrayofplasticscanbeproducedwithawiderangeofcharacteristicsforcountlessapplications.
Table1
Potentialapplicationsofbio-basedcomponentsofmarineoriginforthereplacementofplastics
Lifecycle
stage Category Examples Potentialapplications
Rawmaterials
Macroalgae(seaweed)
Kelp,Wakame,Carrageenanmoss
Bioplastics,gelsforcosmeticsandpharmaceuticals,foodthickeningagents,wastewaterreuse
Microalgaeandothermicroorganisms
Microalgae,bacteria,diatoms
Bioplastics,biofuels,biodegradabledetergents
Minerals,fromtheseabedorcontinentalshelf
Marineclays,silicasandsandquartz,calcite
Fillersinbiocomposites,ceramics,glass
Marineinvertebrates
Sponge
Filtrationandabsorptionmaterials(e.g.,forwaterpurification)
Processing
Biopolymers
Polyhydroxyalkanoates(PHAs),carrageenan
Biodegradablefilms,coatings,fibres
Bioplasticfilms,foilandsheets
Seaweed-basedorPHA-basedfilms
Foodpackaging,carrierbags,agriculturalfilms
Gels,foamsandcreams
Agar-agar
Thickeningorgellingagents,emulsifiers
Naturalfibre
Seaweed-basedyarn,mangrove-basedplaitingmaterial
Textiles,basketwork
Biofuels
Algae-basedbiodiesel,ethanol
Transportationfuels
Manufacturing
Paper
Algae-basedpulpandpaper
Packagingmaterials,printingpaper
Glassandglassware
Glass,madefromsilicasandandquartz
Foodpackaging,construction
Othermanufactures
Chitin-basedfishingnets,seagrassbasketry
Miscellaneous
End-of-life
Fishwaste,forpurposesotherthanfood,feedorfertilizer
Molluscshells,fishscales(e.g.,forextractingChitin)
Fillersinbiocomposites,bioplastics
Source:UNCTADanalysisbasedonAyyakkalaietal.(2024),UNDP(2024),UnitedStatesGeologicalSurvey(2024),Boseetal.(2023),Jianxin,F.etal.(2023),Pip
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